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Cedrica Samuels, a Giselle de Araujo Lima e Souza, aEleonora De Santis, b, c Giovanni Battista Appetecchi, c Steven Greenbaum a aDepartment of Physics and Astronomy, Hunter College, CUNY, New York, USAbDepartment of Chemical Engineering Materials Environment, La Sapienza University of RomecItalian National Agency for New Technologies, Energy and Sustainable Economic Development, Technologies and Devices for Electrochemical Storage (TERINDECACEL) Technical UnitdENEA (Italian National Agency for New Technologies, Energy and Sustainable Economic Development) Current LIB electrolytes face safety and thermal stability limitations that restrict performance under elevated-temperature and extreme-environment conditions, motivating the need for alternative electrolyte systems